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Polar substituent and solvent effects on the kinetics of radical reactions with thiols

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
37
Issue
33
Identifiers
DOI: 10.1016/0040-4039(96)01241-5
Disciplines
  • Chemistry
  • Medicine

Abstract

Graphical abstract The kinetics of hydrogen atom transfers from thiols to the series of substituted radicals 1 in THF and to radical 3 in solvents of various polarity were measured. In water the rate is strongly increased, this is important for trapping reactions under biochemical conditions.

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