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A new binuclear potassium (І) complex with a novel 1D infinite water chain containing (H2O)12clusters

Authors
Journal
Inorganic Chemistry Communications
1387-7003
Publisher
Elsevier
Publication Date
Volume
12
Issue
9
Identifiers
DOI: 10.1016/j.inoche.2009.07.003
Keywords
  • Potassium Complex
  • 2
  • 2′-Azanediyldibenzoic Acid
  • Binuclear Structure
  • Dodecameric Water Cluster
  • Fluorescence
Disciplines
  • Earth Science

Abstract

Abstract A novel 1D infinite water chain made of (H 2O) 12 clusters containing two different chair water hexamers is found in the binuclear coordination compound, [K 2(L) 2(phen) 4]·6H 2O ( 1) (where L = 2,2′-azanediyldibenzoic dianion, phen = 1,10′-phenanthroline), which has been synthesized and structurally characterized by single-crystal X-ray diffraction. The fluorescence spectrum and thermogravimetric analysis (TGA) of the title complex 1 have been also discussed.

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