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Cycloaddition of isoquinolinium salts: homochiral tetralins via dienophiles bearing chiral auxiliaries

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
30
Issue
37
Identifiers
DOI: 10.1016/s0040-4039(01)80543-8

Abstract

Abstract Inverse electron demand cycloaddition of isoquinolinium salts to dienophiles bearing chiral auxiliaries to produce homochiral tetralins are described. The optical purity of the product ranges from 5% to 95+% depending on the nature of the chiral auxiliary.

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