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An infrared and Raman study of 1,1′-disubstituted ferrocene compounds

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
24
Issue
10
Identifiers
DOI: 10.1016/0584-8539(68)80204-1
Disciplines
  • Physics

Abstract

Abstract The infrared (4000-55 cm −1) and Raman (3200-75 cm −1) spectra of 1,1′-dichloro-1,1′-dibromo- and 1,1′-diiodoferrocene are reported. An attempt is made to give a complete vibrational assignment for all fundamental vibrations of these molecules. The results of these assignments are compared to those of 1,1′-dimethylferrocene and of monosubstituted benzenes. The assigned frequencies were tested by utilizing the inequality rule of Whiffen and Steele.

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