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Orthogonal connection of acenes via two-fold Diels-Alder reactions

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
34
Issue
37
Identifiers
DOI: 10.1016/s0040-4039(00)73806-8
Disciplines
  • Mathematics

Abstract

Abstract Novel bis-acenes are described whose subunits are held in an almost orthogonal geometry by silicon-spiro centers. The synthesis involves Diels-Alder active bis-dienes with orthogonal five-membered rings.

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