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Structural Studies of Some Binaphthyl Derivatives

Publication Date
  • Crystal Structures Of Several 1
  • 1'-Binaphthyl Derivatives Have Been Determined
  • In Particular Compounds Which At The 2
  • 2' Positions Have Either Identical Ethoxy Groups Or A Closed Bridged Ether And Furthermore Have Iden
  • 6' Positions
  • The Latter Groups May Be Br
  • Cho
  • Cn Or H
  • As Would Be Expected
  • The Torsional Angle Of The Central 1-1' Bond Varies Considerably In The Open Forms Whereas The Torsi
  • Unfortunately
  • Good Quality Crystals For Structural Studies Are Difficult To Grow And
  • Therefore
  • Rather High Residuals Are Generally Obtained
  • Some Of The Compounds Have Been Tested For Nonlinear Optical Activity (Powder Second Harmonic Genera
  • Shg)


Publications journalExtension.volume journalExtension.pages journalAssociation.title mainResearchArea.mainResearchArea organisations[0] organisations[0].organisation.organisation externalPublication persons[0] persons[0].person.employeeId persons[0].personRole persons[0].firstName persons[0].lastName persons[0].organisations persons[1].personRole persons[1].firstName persons[1].lastName persons[1].externalOrganisation persons[2].personRole persons[2].firstName persons[2].lastName persons[2].externalOrganisation persons[3].personRole persons[3].firstName persons[3].lastName persons[3].externalOrganisation title owner.owner abstract.text[da_DK] typeClassification.typeClassification publicationStatus.publicationStatus publicationDate.year uuid id created modified modifiedBy creator remoteOrigin sourceLicensesDismissed Source: orbit visibility language.language acceptedDuplicate submissionYear publicationCategory.publicationCategory peerReview workflowInformations[0] markedForRevalidation event.event isiIndexed A52 181-181 2576963 Acta Crystallographica Technical/natural sciences 3023 Department of Chemistry 2194256 2485 Author Niels Thorup Department of Chemistry Author T. Bjørnholm CISMI, University of Copenhagen Author K. Bechgaard Risø National Laboratory Author T. Geisler Aalborg University Structural Studies of Some Binaphthyl Derivatives 3023 Department of Chemistry Crystal structures of several 1,1'-binaphthyl derivatives have been determined. In particular compounds which at the 2,2' positions have either identical ethoxy groups or a closed bridged ether and furthermore have identical substitution at the 6,6' positions. The latter groups may be Br, CHO, CN or H. As would be expected, the torsional angle of the central 1-1' bond varies considerably in the open forms whereas the torsion is rather restricted in the closed forms. Unfortunately, good quality

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