Affordable Access

Publisher Website

Assignment of relative configurations to diastereomeric carbinols with lanthanide shift reagent[eu(fod)3]:Application to 1-mesltyl-2-methyl-3-phenyl-1-propanol

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
37
Issue
6
Identifiers
DOI: 10.1016/s0040-4020(01)92059-9
Disciplines
  • Chemistry

Abstract

Abstract Assignment of relative configurations to the diastereomeric racemates ( 1R2R, 1S2S) and ( 1R2S, 1S2R) of 1-mesityl-2-methyl-3-phenyl-1-propanol was carried out, by studing the chemical shifts induced by Eu(fod) 3 an the signal of the Me group in position 2, taking into account a prior estimate of the populations of significant forms in both diastereomers.

There are no comments yet on this publication. Be the first to share your thoughts.