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Ligand field analysis of metal-oxygen interactions—II. Tris(oxalato)chromate(III)

Authors
Journal
Polyhedron
0277-5387
Publisher
Elsevier
Publication Date
Volume
10
Identifiers
DOI: 10.1016/s0277-5387(00)86166-5

Abstract

Abstract Ligand field analysis of [Cr(ox) 3] 3− has been performed using the angular overlap model (AOM) approach. The metal-oxygen interactions were treated as locally anisotropic. The Trees' correction and the explicit treatment of the second coordination sphere were included. A set of parameters was derived which reproduces both the quartet bands and sharp doublet lines. Relationships between structural and spectral data were investigated.

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