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Influence of phase transformations on the radiation induced postpolymerization in the methyl acrylate-alcohol system

Authors
Journal
Polymer Science U S S R
0032-3950
Publisher
Elsevier
Publication Date
Volume
26
Issue
5
Identifiers
DOI: 10.1016/0032-3950(84)90335-6

Abstract

Abstract The influence of phase transitions (devitrification, crystallization, melting) on the postpolymerization of an alcohol solution of methyl acrylate has been investigated. In the temperature region in which polymerization takes place (105–260 K) there is scarcely any recombination of growing polymer chains, and the change in the reaction rate is the result of change in the molecular mobility of reactants accompanying phase transitions.

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