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Aerobic hydroxylation of hydrocarbons catalysed by vanadate ion

Authors
Publisher
Elsevier B.V.
Publication Date
Keywords
  • Alcohols
  • Alkanes
  • Benzene
  • Biomimetics
  • Homogeneous Catalysis
  • Metal Complexes
  • Oxidation
  • Oxygenation
  • Phenol
  • Vanadium Complexes
  • Biochemistry > Catalysis
  • Biochem/0204001
Disciplines
  • Biology

Abstract

Vanadate anion catalyses aerobic hydroxylation of hydrocarbons in acetonitrile in the presence of solid ascorbic acid or zinc and with obligatory participation of pyridine, pyrazine-2-carboxylic acid and acetic acid as mediators of proton and electron transfer. These systems mimic generation of hydroxyl radicals in certain biological processes.

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