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Functional group oxidation using sodium perborate1

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
43
Issue
8
Identifiers
DOI: 10.1016/s0040-4020(01)81484-8

Abstract

Abstract Sodium perborate in acetic acid is an effective reagent for the oxidation of anilines to nitroarenes and of sulphides to either sulphoxides or sulphones. It is also an excellent reagent for the oxidative deprotection of ketone dimethylhydrazones. Baeyer-Villiger oxidation of ketones can be carried out with sodium perborate in either trifluoroacetic acid or acetic acid/trifluoroacetic acid mixtures, and hydroquinones and certain highly substituted phenols are smoothly converted into quinones.

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