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Magnetic circular dichroism of cyclic π-Electron systems. 24. Polarizations and assignments in some pentacyclic and hexacyclic benzenoid hydrocarbons

Authors
Journal
Chemical Physics
0301-0104
Publisher
Elsevier
Publication Date
Volume
60
Issue
2
Identifiers
DOI: 10.1016/0301-0104(81)80116-4
Disciplines
  • Chemistry

Abstract

Abstract Measurements of magnetic circular dichroism and of linear dichroism in stretched polyethylene permitted the assignment of a large number electronic transitions in dibenz[a,c]anthracene, dibenza[a,h]anthracene, dibenz[a,j]anthracene, picene, and benzo[rst]pentaphene. The results are in satisfactory agreement with π-electron calculations. Implications for the analytical chemistry of these hydrocarbons and their simple derivatives are discussed.

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