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4-tert-Butyl-3',4'-bis-(4-methyl-phen-yl)-3,4-dihydro-1H,4'H-spiro-[naphthalene-2,5'-[1,2]oxazol]-1-one.

Authors
  • Akhazzane, Mohamed
  • Zouihri, Hafid
  • Bennani, A Kella
  • Kerbal, Abdelali
  • Al Houari, Ghali
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jul 01, 2011
Volume
67
Issue
Pt 7
Identifiers
DOI: 10.1107/S1600536811025086
PMID: 21837226
Source
Medline
License
Unknown

Abstract

In the title compound, C(30)H(31)NO(2), the cyclo-hexa-none ring in the naphthalene fused-ring system adopts a half-chair conformation, presumably due to conjugation of the benzene ring. The naphthalene ring system makes dihedral angles of 86.63 (7), 65.15 (8) and 63.18 (8)° with respect to the two methyl-benzene planes and the 1,2-oxazole ring system. Inter-molecular C-H⋯O and C-H⋯N hydrogen bonding and C-H⋯π inter-actions stabilize the crystal structure. The H atoms of the two methyl groups of the methyl-phenyl groups are disordered over two positions with equal occupancies.

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