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Synthesis, structure and thermal reduction behaviour of delafossite-type CuRhxAl1− xO2

Authors
Journal
Journal of the Less Common Metals
0022-5088
Publisher
Elsevier
Publication Date
Volume
137
Identifiers
DOI: 10.1016/0022-5088(88)90090-2

Abstract

Abstract Delafossite-type oxides CuRh x Al 1− x O 2 with 0 ⩽ x ⩽ 1 have been synthesized and structurally characterized. The temperature range and the mechanistic course of the thermal reduction have been found to be strongly dependent on the composition of the initial materials. As products, elemental copper, thermally metastable CuRh alloys and Al 2O 3 are formed. These products represent not only interesting metallic materials but also potential bimetallic catalysts.

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