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Rotationally resolved overtone transitions of70GeH4in the visible and near-infrared

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
192
Issue
4
Identifiers
DOI: 10.1016/0009-2614(92)85481-o

Abstract

Abstract The Δν GeH=6, 7 and 8 overtone transitions of natural germane and of mono isotopic germane 70GeH 4 have been measured with rotational resolution by intracavity laser absorption spectroscopy. The Δν GeH=6 and 7 rotational structure is found to be that of a pseudo-symmetric top as expected for this molecule close to the local mode limit. On the other hand the Δν GeH=8 shows a more complicated structure which has not yet been analyzed.

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