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Current-potential curves for a catalytic mechanism with non-Nernstian behavior

Authors
Journal
Journal of Electroanalytical Chemistry
0022-0728
Publisher
Elsevier
Publication Date
Volume
199
Issue
1
Identifiers
DOI: 10.1016/0022-0728(86)87039-5
Disciplines
  • Chemistry

Abstract

Abstract Explicit equations for the current-potential curves for the catalytic mechanism with non-Nernstian behavior have been derived rigorously. These expressions are valid for any value of the rate constants of both the charge transfer and the chemical reaction and they can be used for an electrode expanding in accordance with any power law. Under these conditions the equations used for a DME or a stationary electrode results only as a special case of this general solution. An approach to quantitative kinetic data analysis is also discussed.

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