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Electrochemical behaviour of the electronically and coordinatively unsaturated cluster [Os3(γ-H)(CO)8{Ph2PCH2P(Ph)C6H4})]

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
423
Issue
2
Identifiers
DOI: 10.1016/0022-328x(92)83118-2
Disciplines
  • Chemistry

Abstract

Abstract The electrochemical behaviour of the unsaturated cluster Os 3(H)(CO) 8[Ph 2PCH 2P(Ph)C 6H 4] has been studied by electrochemical and spectroscopic methods. The transformations of the very reactive title compound into the saturated cluster Os 3(H)(CO) 9[Ph 2PCH 2P(Ph)C 6H 4] and Os 3(CO) 10(Ph 2PCH 2PPh 2] by CO addition has been followed step-by-step by cyclic voltammetry.

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