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Infrared spectra of methyl and silyl phosphines

Authors
Journal
Spectrochimica Acta
0371-1951
Publisher
Elsevier
Publication Date
Volume
15
Identifiers
DOI: 10.1016/s0371-1951(59)80300-3
Disciplines
  • Physics

Abstract

Abstract The infrared spectrá of methyl and silyl phosphines in the gas phase have been obtained over the region from 300 to 4000 cm −1 at prism resolution. A number of vibrational assignments have been made on the basis of a C s model, although in several instances overlapping of bands permits only approximate values for some band centers. The complex absorption from 400 to 500 cm −1 in SiH 3PH 2 suggests the possibility that the overtone of the internal torsion may lie in this region.

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