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An efficient approach to bridged-bicyclic rings via intramolecular diazo ketone insertion

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
43
Issue
26
Identifiers
DOI: 10.1016/s0040-4039(02)00878-x

Abstract

Abstract A regioselective intramolecular diazo ketone insertion reaction of chiral cyclohexenones is described. The methodology shows potential utility in the syntheses of bicyclo[4.2.1]nonan-9-one, bicyclo[4.3.1]decan-10-one and cyclooctanoid rings.

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