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Asymmetric total synthesis of the individual diastereoisomers of hypoglycin A.

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
50
Issue
41
Identifiers
DOI: 10.1016/s0040-4020(01)89313-3

Abstract

The individual diastereoisomers that constitute the unusual methylenecyclopropane containing α-amino acid hypoglycin A, ( 1) and ( 2), have been synthesised utilising the Sharpless epoxidation to permit an asymmetric methylenecyclopropane synthesis.

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