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Empirical determination of low J values of 13CH4 transitions from jet cooled and 80 K cell spectra in the icosad region (7170–7367 cm−1)

Authors
Journal
Journal of Quantitative Spectroscopy and Radiative Transfer
0022-4073
Publisher
Elsevier
Identifiers
DOI: 10.1016/j.jqsrt.2014.07.012
Keywords
  • 13Ch4
  • Methane
  • Cold Spectra
  • Ch4
  • Hitran
Disciplines
  • Physics

Abstract

Abstract The absorption spectrum of 13CH4 was recorded at two low temperatures in the icosad region near 1.38µm, using direct absorption tunable diode lasers. Spectra were obtained using a cryogenic cell cooled at liquid nitrogen temperature (80K) and a supersonic jet providing a 32K rotational temperature in the 7173–7367cm−1 and 7200–7354cm−1 spectral intervals, respectively. Two lists of 4498 and 339 lines, including absolute line intensities, were constructed from the 80K and jet spectra, respectively. All the transitions observed in jet conditions were observed at 80K. From the temperature variation of their line intensities, the corresponding lower state energy values were determined. The 339 derived empirical values of the J rotational quantum number are found close to integer values and are all smaller than 4, as a consequence of the efficient rotational cooling. Six R(0) transitions have been identified providing key information on the origins of the vibrational bands which contribute to the very congested and not yet assigned 13CH4 spectrum in the considered region of the icosad.

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