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A combined, 6-exo-digradical cyclization-palladium catalyzed allylic amination, approach to aminocarbasugar analogs: synthesis of novelN-substituted aminocyclitols fromd-mannose

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
43
Issue
44
Identifiers
DOI: 10.1016/s0040-4039(02)01919-6

Abstract

Abstract A novel approach, which features a stereoselective 6- exo- dig radical cyclization and a palladium-catalyzed allylic amination, permits a six steps synthesis of aminocyclitol analogs from d-mannose.

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