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7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
66
Issue
12
Identifiers
DOI: 10.1107/s1600536810048002
Keywords
  • Organic Papers

Abstract

In the title compound, C24H18N2O4·CHCl3, the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The mol­ecule has a Z configuration about the C=N bond. In the crystal, mol­ecules are linked by inter­molecular O—H⋯N=C hydrogen bonds between the imino moiety and hy­droxy groups. Inter­molecular C—Cl⋯C inter­actions between Cl atoms of the CHCl3 mol­ecule and C atoms of the naphthalene rings are also present [Cl⋯C = 3.353 (2) and 3.326 (19) Å]. The nitro group and the chloro­form solvent mol­ecule are disordered over two positions with site occupancies of 0.884 (4) and 0.116 (4).

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