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A cross-aldol type reaction of alkenyl sulfide with trimethylsilyl enol ether.

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
27
Issue
26
Identifiers
DOI: 10.1016/s0040-4039(00)84708-5

Abstract

β-Phenylthio ketones ( 4 ) were obtained by the successive treatment of alkenyl sulfides ( 1 ) with TiCl 4-RCH (R = Me or t-Bu) and trimethylsilyl enol ethers ( 3 ) via thionium ion intermediates (2).

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