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Cleavage by halogens of carbon—cobalt bonds in organometallic complexes of cobalt(III):III. Kinetics and mechanism of the reactions of organobis(dimethylglyoximato)cobalt(III) complexes with iodine in chloroform

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
139
Issue
2
Identifiers
DOI: 10.1016/s0022-328x(00)85469-8

Abstract

Abstract The kinetics of the reaction between organocobaloximes, RCo(DH) 2H 2O, and iodine have been investigated. They reveal the participation of an RCo(DH) 2H 2O · I 2 intermediate which undergoes intramolecular transalkylation and acts as an electrophile towards a second organocobaloxime molecule. The trend in reactivity as the R group is varied is discussed.

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