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Identification of crystalline phases found in multicomponent AlF3-based glasses

Authors
Journal
Journal of Non-Crystalline Solids
0022-3093
Publisher
Elsevier
Publication Date
Volume
161
Identifiers
DOI: 10.1016/0022-3093(93)90669-o

Abstract

Abstract Glasses in the system AlF 3[MgF 2CaF 2SrF 2BaF 2]YF 3 (i.e., AMCSBY) have been optimised to reduce devitrification on quenching the melt. Cast specimens are in large part crystal-free. Nevertheless, microcrystallites tend to be present in a characteristics distribution within the glass bulk. The morphology and identity of these crystals are discussed especially in relation to the crystallisation which occurs in reheating the glass.

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