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Double asymmetric induction in the osmylation of -γ-alkoxy-α,β-unsaturated esters

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
44
Issue
22
Identifiers
DOI: 10.1016/s0040-4020(01)86219-0

Abstract

Abstract OsO 4 promoted cis-dihydroxylation of enantiomerically pure (E)-α,β- unsaturated esters derived from alkoxyaldehydes occurs with noticeable levels (up to⩾ 45:1) of stereoselection when carried out in the presence of alkaloid derived ligands. Matching and mismatching substrate-ligand pairs have been identified.

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