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Quadrupole interaction in vanadium-based laves phase hydrides

Authors
Journal
Solid State Communications
0038-1098
Publisher
Elsevier
Publication Date
Volume
71
Issue
4
Identifiers
DOI: 10.1016/0038-1098(89)91022-3

Abstract

Abstract The static and dynamic parts of 51V quadrupole interaction in the C15-type compounds TaV 2H x (D x ) are studied as functions of H(D) content. It is found that the static electric-field gradient (EFG) at V sites changes sign near x = 0.7. The H(D) contributions to the measured EFG in TaV 2H x (D x ) and the related compounds HfV 2H x (D x ) and ZrV 2H x (D x ) are estimated from the experimental data and analyzed in terms of the point-charge model.

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