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Effects of iodide ion and amines on the free radical alkylation of 1,4-enediones by alkylmercury halides

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
31
Issue
44
Identifiers
DOI: 10.1016/s0040-4039(00)97040-0

Abstract

Abstract Iodide ion promotes the photostimulated reductive alkylation of α,⨿-unsaturated ketones by electron transfer from RHgl 2- to the adduct enolyl radicals. Amines such as Dabco can promote oxidative alkylation by removal of a proton from the adduct radicals.

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