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The near-infrared spectrum of NeHCl

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
147
Issue
5
Identifiers
DOI: 10.1016/0009-2614(88)85014-0
Disciplines
  • Physics

Abstract

Abstract The near-infrared spectrum of jet-cooled NeHCl is reported. The HCl stretching fundamental and three combination bands are observed and analyzed to determine rotational constants and vibrational frequencies including those of the van der Waals stretching and bending modes. An unusual intensity distribution is observed, in which the fundamental is weak and the combination bands are strong; in part this is the result of nearly free internal rotation of the HCl subunit within the complex.

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