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Comment of the use of dichloromethyl methyl ether as formylating agent

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  • Chemie Und Pharmazie
  • Ddc:540

Abstract

In contrast to normal alkenes, dialkylacetylenes can be formylated with dichloromethyl methyl ether (1) in the presence of 1.2 equivalents of boron trichloride. A rationalisation for the different behaviour of alkenes and alkynes arises from the NMR specktroscopic investigation of the reaction intermediates.

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