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Synthesis and characterization of [RuCl2(picoline)4] complexes: Crystal structure of [RuCl2(β-pic)4]

Authors
Journal
Polyhedron
0277-5387
Publisher
Elsevier
Publication Date
Volume
24
Issue
12
Identifiers
DOI: 10.1016/j.poly.2005.03.092
Keywords
  • Ruthenium
  • Picoline
  • X-Ray Structure
  • Tddft Method

Abstract

Abstract The reaction of the [RuCl 2(PPh 3) 3] complex with picolines has been examined. New ruthenium(II) complexes – [RuCl 2(C 6H 7N) 4] have been obtained and characterized by IR, 1H NMR and UV–Vis measurements. The crystal structure of the [RuCl 2(β-pic) 4] complex has been determined. The electronic spectra of the complexes have been calculated by the TDDFT method.

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