Affordable Access

Publisher Website

An EPR study of cadmium silicate and phosphate glasses

Authors
Journal
Journal of Non-Crystalline Solids
0022-3093
Publisher
Elsevier
Publication Date
Identifiers
DOI: 10.1016/0022-3093(80)90394-4

Abstract

Abstract Using the EPR technique, a series of irradiated silicate, phosphate and alumophosphate cadmium-containing glasses with an admixture of copper and halogens have been investigated. We have observed the EPR spectrum due to Cd +, determined the hfs constant for Cd + as a function of glass composition, detected a change in the structural position of Cd + with varying Al 2O 3 concentration. It has been found that the glass composition affects the degree of distortion of the PO 4 tetrahedron which manifests itself in a change in the hfs constant for the PO 2− 3 radical. A new phosphorus radical with the parameters A 1 = 312 G and g 1 = 2.0034 has been observed.

There are no comments yet on this publication. Be the first to share your thoughts.

Statistics

Seen <100 times
0 Comments

More articles like this

EPR study of molybdenum-lead-phosphate glasses

on Journal of Non-Crystalline Sol... Jan 01, 2008

EPR study of Ti3+ions formed under beta irradiatio...

on Journal of Non-Crystalline Sol... Jan 01, 2011

Cadmium sulfide-selenide doped glasses: silicate a...

on Journal of Non-Crystalline Sol... Jan 01, 1997

EPR study of structural defects in ion-implanted m...

on Journal of Non-Crystalline Sol... Jan 01, 1992
More articles like this..