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2D-correlation analysis applied to in situ and operando Mossbauer spectroscopy

Authors
  • Aldon, Laurent
  • Perea, Alexis
Publication Date
Feb 01, 2011
Identifiers
DOI: 10.1016/j.jpowsour.2010.08.013
OAI: oai:HAL:hal-00657362v1
Source
HAL-SHS
Keywords
Language
English
License
Unknown
External links

Abstract

In this paper we propose a new way for Mossbauer data treatment when numerous experimental spectra are recorded in operando conditions depending on a perturbation. In our example, the perturabation is the Li amount extracted from a positive electrode material LiFe(0.75)Mn(0.25)PO(4). In other cases perturbation could be the recording temperature, the pressure or kinetic parameter or even time for isothermal experiments. From analysis of both synchronous and asynchronous 2D-correlation spectra, we can focus our attention on the intensity variations at some specific positions deduced from cross-peaks. This analytical method is very powerful when overlap between absorption lines is observed. This is typically the case when Fe(2+)/Fe(3+) contributions are simultaneously present in a Mossbauer spectrum at lower velocities.

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