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The mechanism of the photoinduced hydrogenation of 2,4-hexadiene catalyzed by chromium carbonyl complexes

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
70
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)83373-2

Abstract

Abstract The selectivity of the reaction with respect to the three isomers of 2,4-hexadiene depends on the precatalyst used and is discussed in the light of a general reaction scheme. The behaviour of this linear diene is compared with that of 1,3-cyclohexadiene.

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