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Organocobalt compounds:VI. Some oxidative and thermal degradations of methinylnonacarbonyltricobalts and (phenylacetylene)hexacarbonyldicobalt

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
73
Issue
3
Identifiers
DOI: 10.1016/s0022-328x(00)83838-3

Abstract

Abstract Oxidative and thermal degradation of methinylnonacarbonyltricobalts, RCCo 3 (CO) 9, yield inter alia, the acetylenes RCCR derived from coupling of two RC groups. Ceric oxidation of (phenylacetylene)hexacarbonyldicobalt is accompanied by carbonyl insertion yielding 2-phenylpropionate.

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