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Skeletal rearrangements in the nitrations of α,β-unsaturated esters

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
36
Issue
17
Identifiers
DOI: 10.1016/0040-4039(95)00421-8

Abstract

Abstract Reaction of α,β-unsaturated esters with nitronium tetrafluoroborate in acetonitrile at −16°C affords products of skeletal cationic rearrangements suggesting the intermediacy of highly reactive α-carbonyl cations.

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