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Ultraviolet absorption spectrum of gaseous IrF6in the 200–500 nm region

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
52
Issue
10
Identifiers
DOI: 10.1016/0584-8539(96)01681-9
Keywords
  • Charge-Transfer Transitions
  • Hexafluorides
  • Ultraviolet Spectroscopy
Disciplines
  • Physics

Abstract

Abstract The theory of the electronic transitions of iridium hexafluoride is briefly reviewed. Then, we present the ultraviolet absorption spectrum of this molecule in the gas phase over the 20 000–50 000 cm −1 region. Some new electronic transitions are observed. Their physical origin is discussed and some values of the v 1( A 1 g ) totally symmetric stretching mode frequency in these highly excited electronic states are given.

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