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Palladium-catalyzed stereospecific ring expansion reaction of allenylcyclobutanols with aryl iodides: a novel route to the α-substituted cyclopentanones with quaternary carbon stereocenters

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
41
Issue
26
Identifiers
DOI: 10.1016/s0040-4039(00)00779-6
Keywords
  • Cyclopentanones
  • Palladium And Compounds
  • Rearrangements
  • Ring Transformations

Abstract

Abstract Stereoselective synthesis of α-substituted cyclopentanones with quaternary carbon stereocenters has been achieved by the palladium-catalyzed rearrangement of allenylcyclobutanols with aryl iodides.

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