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The singlet oxygen conversion of oxazoles to triamides. Application in the synthesis of (±)-pyrenolide C. assignment of stereochemistry.

Authors
Journal
Tetrahedron
0040-4020
Publisher
Elsevier
Publication Date
Volume
48
Issue
38
Identifiers
DOI: 10.1016/s0040-4020(01)80489-0
Disciplines
  • Chemistry

Abstract

Abstract Pyrenolide C has been synthesized for the first time using an oxazole template to construct the framework of the ten-membered unsaturated lactone system. The stereochemical assignment of the allylic alcohol substituent, based on the mode of synthesis, has been confirmed by NMR studies.

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