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Anodic polarisation of the lithium/lithium nitride interface:Part I. Electrochemical measurements

Authors
Journal
Journal of Electroanalytical Chemistry
0022-0728
Publisher
Elsevier
Publication Date
Volume
129
Identifiers
DOI: 10.1016/s0022-0728(81)80022-8

Abstract

Abstract The kinetics of lithium transport across the interface formed by melting lithium on to a lithium nitride sinter has been studied using a linear potential sweep technique. The current-voltage curve obtained was corrected for the ohmic resistance obtained from the high-frequency intercept of the complex plane impedance diagram measured at E=0 mV (vs. a Li/Li + reference electrode). A model which allows the calculation of the product of concentration and diffusion coefficient to be calculated is proposed to account for the observed behaviour.

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