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Single crystal EPR of studies Ni(II) in hexaimidazole zinc(II)dichloride tetrahydrate: a case of rhombic distortion

Authors
Journal
Solid State Communications
0038-1098
Publisher
Elsevier
Publication Date
Volume
122
Identifiers
DOI: 10.1016/s0038-1098(02)00095-9
Keywords
  • E. Electron Paramagnetic Resonance
  • A. Ni (Ii)
  • A. Single Crystal
  • E. Room Temperature

Abstract

Abstract Single crystal electron paramagnetic resonance of Ni(II) doped hexaimidazole zinc(II)dichloride tetrahydrate has been studied at room temperature. The material exhibited rhombic g and D tensors. The spin Hamiltonian parameters obtained from single crystal rotations are g 11=2.3691, g 22=2.2105, g 33=1.9409 and D 11=244.07, D 22=24.98, D 33=−269.05 mT. It has been inferred that Ni(II) replaces zinc(II) substitutionally.

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