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Aqua­chlorido{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­dimethyl­idyne)]diphenolato-κ2 O 1,N,N′,O 1′}cobalt(III) monohydrate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
4
Identifiers
DOI: 10.1107/s1600536809011167
Keywords
  • Metal-Organic Papers

Abstract

The title compound, [Co(C18H18N2O4)Cl(H2O)]·H2O, contains a distorted octa­hedral cobalt(III) complex with a 6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­dimethyl­idyne)]diphenolate ligand, a chloride and an aqua ligand, and also a disordered water solvent mol­ecule (half-occupancy). The CoIII ion is coordinated in an N2O3Cl manner. Weak O—H⋯O hydrogen bonds may help to stabilize the crystal packing.

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