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Tandem intermolecular Suzuki coupling/intramolecular vinyl triflate-arene coupling

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Treatment of a benzyl substituted meso-ditriflate with boronic acids in the presence of palladium acetate, triphenylphosphine and caesium fluoride results in intermolecular Suzuki coupling followed by vinyl triflate-arene cyclisation to provide, in high yields, single regioisomers of tricycliccarbocycles.

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