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N,N′-Dibenzyl-N,N′-dimethyl-N′′-(p-tol­yl)phospho­ric triamide

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
67
Issue
12
Identifiers
DOI: 10.1107/s1600536811046046
Keywords
  • Organic Papers

Abstract

The asymmetric unit of the title compound, C23H28N3OP, contains two independent mol­ecules with significant conformational differences. For example, the torsion angles N—C—C—C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol­ecule and 76.5 (7) and 97.4 (7)° in the other. In each mol­ecule, the P atom exhibits a distorted tetra­hedral conformation [the bond angles at P are in the ranges 104.7 (2)–115.2 (2) and 105.1 (2)–115.1 (2)° in the two molecules], and the phosphoryl group and the N—H group adopt an anti orientation with respect to one another. In the crystal, mol­ecules are linked via N—H⋯O(P) hydrogen bonds, forming a chain parallel to the a axis.

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