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First total synthesis and reassignment of absolute configuration of diosniponol A and B

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Identifiers
DOI: 10.1016/j.tetlet.2014.04.065
Keywords
  • Diosniponol A And B
  • Anti-Neuroinflammatory Effects
  • Prins Cyclization
  • Wittig Reaction
  • Keck Allylation

Abstract

Abstract Enantioselective first total synthesis of diosniponol A and B has been achieved starting from commercially available vanillin. Wittig reaction, Keck allylation, and Prins cyclization reactions are the key steps involved in the target synthesis.

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