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Anomalous internuclear distances in 1,8-substituted naphthalenes and 1,4-substituted phenanthrenes

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
28
Issue
49
Identifiers
DOI: 10.1016/s0040-4039(00)61857-9

Abstract

Abstract Chlorine and bromine atoms in peri (1,8) positions of naphthalene exhibit smaller internuclear distances than those in bay (4,5) positions of phenanthrene. This anomalous result may be due to the anisotropy of van der Waals' surfaces.

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