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FTIR absorption spectra of ClCS in an argon matrix

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
201
Identifiers
DOI: 10.1016/0009-2614(93)85112-2

Abstract

Abstract ClCS was produced with a pulsed jet—dc discharge of Cl 2CS/Ar, CS 2/Cl 2/Ar, and CS 2/CCl 4/Ar and deposited forming an argon matrix. The vibrational frequencies for ν 1 and ν 3 are determined to be 1189.3 and 632.1 cm −1, respectively. Isotopic substitution experiments and normal coordinate calculations were performed to confirm the assignments.

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