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Removal of antimony (III) by multi-walled carbon nanotubes from model solution and environmental samples

Authors
Journal
Chemical Engineering Research and Design
0263-8762
Publisher
Elsevier
Volume
91
Issue
7
Identifiers
DOI: 10.1016/j.cherd.2013.02.007
Keywords
  • Carbon Nanotubes
  • Sb(Iii)
  • Adsorption
  • Kinetics
  • Environmental Samples
Disciplines
  • Ecology
  • Geography

Abstract

Abstract Multi-walled carbon nanotubes (MWCNTs) are used for the adsorption and removal of Sb(III) from model solutions and real environmental samples. The effects of different factors that affect the adsorption process; the results showed that most of the Sb(III) ions were removed from the solution within 30min, at pH 7.0, using 200mg MWCNTs. Further, it was observed that the adsorption process was greatly enhanced by lowering the solution temperature, which indicated the exothermic nature of the adsorption. The adsorption study was analyzed kinetically, using different kinetic models, and the results showed that the adsorption of Sb(III) by MWCNTs from the model solution followed pseudo-second-order kinetics with good correlation coefficients. In addition, it was found that the adsorption of Sb(III) occurred in more than one step, including the liquid film diffusion of the Sb(III) ions from the aqueous phase through the liquid film around the MWCNTs and further intra-particle diffusion through the nanotubes’ bundles and aggregates.

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