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Gas phase characterization by photoelectron spectroscopy of unhindered α-heterosubstituted germylenes[1]

Authors
Journal
Journal of Molecular Structure
0022-2860
Publisher
Elsevier
Publication Date
Volume
782
Issue
1
Identifiers
DOI: 10.1016/j.molstruc.2004.11.025
Keywords
  • Uv-Photoelectron Spectroscopy
  • Flash Vacuum Thermolysis
  • Dft Calculations
  • Germylenes
Disciplines
  • Physics

Abstract

Abstract Two unhindered α-heterosubstituted (O and S) cyclic germylenes have been generated and characterized by the combination of flash vacuum thermolysis of stable germacyclopentenes and ultraviolet photoelectron spectroscopy. This coupling associated with ab initio calculations with the hybrid functional B3LYP and the 6-311G(d) basis set allows to predict the electronic properties of the generated germylenes. The thermodynamic stabilization of these reactive molecules by electronic delocalization of the heteroatom π lone pairs within the 4π orbitals of the germanium atom is clearly shown.

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